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Once in Vernazza find the trail which leads south to Corniglia. The spot is about 0.3 - 0.5 from the trail's beginning. It's pretty obvious. You'll be facing North - North West.
Specifically, you'll notice a metal railing to prevent people from falling off the cliff. However, past the railing there is a nice spot just big enough for a couple tri-pods. This is where I took the photo! I don't recommend doing this! If you do decide to go beyond the railing as I did, be extremely careful because there is very little space. If you make a wrong step you will plummet ~30-50 meters off the cliff to your death.